TE4152 Advanced Thermodynamics Syllabus:

TE4152 Advanced Thermodynamics Syllabus – Anna University PG Syllabus Regulation 2021

COURSE OBJECTIVES:

 To achieve an understanding of basic principle and scope of thermodynamics.
 To predict the availability and irreversibility associated with the thermodynamic processes.
 To analyse the properties of ideal and real gas mixtures and to understand the basic concepts of thermal systems

UNIT I THERMODYNAMIC PROPERTY RELATIONS

Thermodynamic Potentials, Maxwell relations, Generalised relations for changes in Entropy, Internal Energy and Enthalpy, Generalised Relations for Cp and Cv, Clausius Clapeyron Equation, Joule Thomson Coefficient, Bridgeman Tables for Thermodynamic Relations.

UNIT II REAL GAS BEHAVIOUR AND MULTI-COMPONENT SYSTEMS

Equations of State (mention three equations), Fugacity, Compressibility, Principle of Corresponding States, use of generalised charts for enthalpy and entropy departure, fugacity coefficient, Lee-Kesler generalised three parameter tables. Fundamental property relations for systems of variable composition, partial molar properties, Real gas mixtures, Ideal solution of real gases and liquids, Equilibrium in multi-phase systems, Gibb’s phase rule for non-reactive components.

UNIT III AVAILABILITY ANALYSIS

Introduction, Reversible work, Availability, Irreversibility and Second – Law Efficiency for a closed System and Steady-State Control Volume. Availability Analysis of Simple Cycles. Chemical availability of closed and control volume. Fuel Chemical availability, Evaluation of the availability of hydrocarbon fuels.

UNIT IV FUEL – AIR CYCLES AND THEIR ANALYSIS

Ideal Models of Engine Processes, Fuel–Air Cycle Analysis – SI Engine Cycle Simulation, CI Engine Cycle Simulation, Results of Cycle Calculations, Availability Analysis of Engine Processes – Availability Relationships – Entropy changes in Ideal Cycles – Availability Analysis of Ideal Cycles.

UNIT V THERMO CHEMISTRY

Ideal gas laws and properties of Mixtures, Combustion Stoichiometry, Application of First Law of Thermodynamics – Heat of Reaction – Enthalpy of Formation – Adiabatic flame temperature. Second law of Thermodynamics applied to combustion – entropy, maximum work and efficiency Chemical equilibrium: – Equilibrium constant evaluation Kp&Kf, Equilibrium composition evaluation of ideal gas and real gas mixtures.

COURSE OUTCOMES:

On successful completion of this course the student will be able to
1. Apply the law of thermodynamics to thermal systems.
2. Analyse the actual thermodynamic cycles
3. Design and analyse a multi component thermodynamic system
4. Apply the thermodynamics concepts in automotive systems
5. Understand and analyse the combustion of different fuels

REFERENCES:

1. Kenneth Wark., J.R, Advanced Thermodynamics for Engineers, McGraw-Hill Inc., 1995.
2. K.Annamalai, I.K.Puri, M.A.Jog, Advanced Thermodynamics Engineering, Second Edition, CRC Press, 2011.
3. Advanced Thermodynamics, S.S. Thipse, Narosa Publishing Home Pvt. Ltd., 2013
4. Yunus A. Cengel and Michael A. Boles, Thermodynamics, McGraw-Hill Inc., 2006.
5. B.P. Pundir, I.C. engine combustion and emissions. Bejan, A., Advanced Engineering
6. Thermodynamics, John Wiley and Sons, 1988.
7. Holman,J.P., Thermodynamics, Fourth Edition, McGraw-Hill Inc., 1988.