NT4102 Physics and Chemistry of Materials Syllabus:

NT4102 Physics and Chemistry of Materials Syllabus – Anna University PG Syllabus Regulation 2021

COURSE OBJECTIVES:

 To gain knowledge on Physical and chemical aspects of Nanomaterials.
 To know about diffusion and surface defects, nanostructures and Nanosystems.

UNIT I PHYSICS ASPECTS

Size effect on thermal, electrical, electronic, mechanical, optical and magnetic properties of nanomaterials – surface area and aspect ratio- band gap energy- quantum confinement size effect.

UNIT II CHEMISTRY ASPECTS

Photochemistry and Electrochemistry of nanomaterials–Ionic properties of nanomaterials Nano catalysis-Nanoscale heat transfer-Electron transport in transition metals and semi conducting nanostructures.

UNIT III DIFFUSION AND SURFACE DEFECTS

Fick’s Law-mechanisms of diffusion-influence of pressure and temperature-Kirkendall effect- surface defects in nanomaterials- effect of microstructure on surface defects-interfacial energy.

UNIT IV NANOSTRUCTURES

Classifications of nanomaterials-Zero dimensional, one-dimensional and two dimensional nanostructures-Kinetics in nanostructured materials-multi layer thin films and super lattice-clusters of metals, semiconductors and nanocomposites.

UNIT V NANOSYSTEMS

Nanoparticles through homogeneous and heterogeneous nucleation-Growth controlled by surface and diffusion process- Oswal dripening process- influence of reducing agents solid state phase segregation-Mechanisms of phase transformation-grain growth and sintering –precipitation in solid solution-Hume-Rothery rule.

TOTAL: 45PERIODS

COURSE OUTCOMES:

CO1:Gaining knowledge on physical and chemical aspects of Nanomaterials
CO2: Students will understand about the diffusion and surface defects in nanomaterials
CO3: Students will learn about various kinds of nanostructures and Nanosystems

REFERENCES:

1. K.W.Kolasinski,“SurfaceScience:FoundationsofCatalysisandNanoscience”,WileyLondon, 2002.
2. G. Cao, Nanostructures & Nanomaterials: Synthesis, Properties & Applications, Imperial College Press,London,2004.
3. Joel I.Gersten, “The Physics and Chemistry of Materials”,Wiley, London 2001.
4. A.S. Edelstein and R.C. Cammarata, “Nanomaterials: Synthesis, Properties and Applications”, Institute of Physics Pub., London,1998.
5. S.Yangand P.Shen: “Physics and Chemistry of Nanostructured Materials”, Taylor & Francis, NewYork,2000.
6. G.A. OzinandA.C. Arsenault, “Nanochemistry: A chemical approachto Nanomaterials”, Royal Society of Chemistry,London2005.
7. AtkinsPeter, PaulaJulio Physical Chemistry,